Efecto de iones y concentración de proteína Ps19, una proteína de la concha de Pteria sterna, en los polimorfos de carbonato de calcio
Polimorfos de carbonato de calcio en Concha Nácar
DOI:
https://doi.org/10.18633/biotecnia.v25i2.1885Palabras clave:
Molusco, Proteína de la concha, carbonato de calcio, cristalizacion, nácarResumen
El carbonato de calcio está presente en muchas estructuras biológicas, como la concha de bivalvo, que se compone principalmente de dos polimorfos de CaCO3: calcita y aragonito. Sin embargo, existen otras formas de carbonato de calcio como vaterita y carbonato de calcio amorfo (ACC) que no se reportan comúnmente. La selección de polimorfos está influenciada por la concentración de sal, los iones cofactores y la presencia de proteínas de la matriz de la cubierta (SMP) que regulan la deposición de carbonato de calcio, entre otros factores. En este estudio, se evaluó la cristalización in vitro de carbonato de calcio de cuatro soluciones salinas diferentes en dos molaridades con diferentes concentraciones la proteína Ps19, una proteína extraída insoluble de la concha de Pteria sterna, descrita anteriormente como promotora de la cristalización de plaquetas de aragonita. Las cristalizaciones in vitro mostraron que Ps19 es capaz de inducir la deposición de aragonita y calcita de forma dependiente de la dosis, pero también de vaterita en determinadas condiciones, actuando como promotor e inhibidor de la cristalización. Los resultados contribuyen a comprender cómo Ps19 controla la precipitación de polimorfos de calcio en el crecimiento de la capa prismática y de nácar de la concha de P. sterna.
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