Aplicación potencial de residuos agroforestales en la adsorción de anilina
DOI:
https://doi.org/10.18633/biotecnia.v26.2416Palabras clave:
aminas aromáticas, residuos, mecanismos de adsorción, carbon activado, isotermasResumen
Se sintetizó y caracterizó carbón activado (CAA) de bajo costo a base de residuos agroforestales para la eliminación de anilina (AN), la cual es una sustancia tóxica para la salud y el medio ambiente. Se evaluó el efecto del tiempo de contacto (1, 2, 6, 12 y 24 h), pH (2 ,4 ,6 y 8) con 1, 5 y 10 mg/L de AN. El mecanismo de adsorción de AN en CAA y los carbones comerciales (CAG y CAP) fue evaluado y comparado con las isotermas de Langmuir, Freundlich y Temkin. Los resultados mostraron que la eliminación de AN aumentó con la disminución del pH, el CAA alcanzó una remoción máxima de 90 %. El CAA resultó en una eficiencia similar al CAG > 90 % a 1 y 5 mg/L. El modelo de Langmuir mostró el mejor ajuste con una R2 de 0.98. Estos modelos explican que el mecanismo de adsorción de AN sobre CAA es homogéneo, y se produce adsorción monocapa, alcanzando una capacidad, alcanzando una capacidad máxima de 1.20 y 1.16 mg/g para CAG y CAP respectivamente, con un posible mecanismo endotérmico sugerido por Temkin. El CAA podría considerarse un adsorbente eficaz y económico en la eliminación del AN.
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